Cutting Compound

Material name: Ultra Cutting Creme

Code: 1319

Issue date: 10-10-2014

Revision date: 09-08-2015 (Version 02, supersedes 06-24-2015)

Document type: Safety Data Sheet (SDS EU)

24 hr Emergency Assistance (New Zealand): National Poison Control Center: 0800 Poison [764 766]

Trade name / designation of mixture: Ultra Cutting Creme

Registration number: Not applicable

Synonyms: None

Identified uses: Compound, polishing cru00e8me

Uses advised against: None known

Supplier (Manufacturer):
Presta Products
361 Fairview Ave, Barberton, OH 44203, US

Division phone: 800-253-2526
Fax: 330-777-8317
E-mail: msdsinfo@malcopro.com
Contact person: Not available

Emergency telephone (international): +1-800-424-9300

Distributor in New Zealand:
Envirochem International (NZ) LTD
41 Angle Street, Onehunga, Auckland, New Zealand
Telephone: +64 9 262 0800
Fax: +64 9 262 0802

Classification according to Regulation (EC) No 1272/2008:

• Specific target organ toxicity u2013 repeated exposure: Category 1 (STOT RE 1)
  H372: Causes damage to organs through prolonged or repeated exposure.

Hazard summary: Causes damage to organs through prolonged or repeated exposure. Occupational exposure to the substance or mixture may cause adverse health effects.

Label elements (CLP):

Contains: Solvent Naphtha (Petroleum), Medium Aliph.

Signal word: Danger

Hazard statements:

• H372: Causes damage to organs through prolonged or repeated exposure.

Precautionary statements – Prevention:

• P260: Do not breathe mist or vapor.
• P264: Wash thoroughly after handling.
• P270: Do not eat, drink or smoke when using this product.

Precautionary statements – Response:

• P314: Get medical advice/attention if you feel unwell.

Precautionary statements – Storage: Store away from incompatible materials.

Precautionary statements – Disposal:

• P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental label information: None.

Other hazards: None known.

Mixtures:

Composition comments: The full text for all R- and H-phrases is provided in Section 16 of the original SDS.

Abbreviations: CLP = Regulation (EC) No. 1272/2008; DSD = Directive 67/548/EEC; M = M-factor; vPvB = very persistent and very bioaccumulative; PBT = persistent, bioaccumulative and toxic; # = substance assigned Community workplace exposure limit(s).

General information: If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

Inhalation: Move to fresh air. Call a physician if symptoms develop or persist.

Skin contact: Wash off with soap and water. Get medical attention if irritation develops and persists.

Eye contact: Rinse cautiously with water. Get medical attention if irritation develops and persists.

Ingestion: Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects (acute and delayed): Prolonged exposure may cause chronic effects.

Medical attention and special treatment: Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

General fire hazards: No unusual fire or explosion hazards noted.

Suitable extinguishing media: Powder, alcohol-resistant foam, carbon dioxide (COu2082).

Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire.

Special hazards arising from the substance or mixture: During fire, hazardous gases may be formed.

Protective equipment for firefighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

Special firefighting procedures: Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials.

For non-emergency personnel: Keep unnecessary personnel away. Do not breathe mist or vapour. See Section 8 for personal protection.

For emergency responders: Keep unnecessary personnel away. Use personal protection recommended in Section 8.

Environmental precautions: Avoid discharge into drains, water courses or onto the ground.

Methods and materials for containment and cleaning up:

• Use water spray to reduce vapours or divert vapour cloud drift.
• Large spills: Stop the flow of material if this can be done without risk. Dike the spilled material where possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place in containers. After product recovery, flush area with water.
• Small spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
• Never return spills to original containers for re-use.

For personal protection, see Section 8. For waste disposal, see Section 13.

Precautions for safe handling: Provide adequate ventilation. Do not breathe mist or vapour. Avoid prolonged exposure. When using, do not eat, drink or smoke. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.

Conditions for safe storage (including incompatibilities): Store in original, tightly closed container. Store away from incompatible materials (see Section 10).

Specific end use(s): Compound, polishing cru00e8me, as identified in Section 1.

8.1 Control parameters – Occupational Exposure Limits (excerpted as provided):

Austria. MAK List, OEL Ordinance (GwV), BGBl. II, no. 184/2001nComponents                 Type  Value      FormnAluminum Oxide; Alumina    MAK   5 mg/m3    Respirable fraction.n(CAS 1344-28-1)                  5 mg/m3    Respirable fume.n                                 10 mg/m3   Inhalable fraction.n                           STEL  20 mg/m3   Inhalable fraction.n                                 10 mg/m3   Respirable fume.n                                 10 mg/m3   Respirable fraction.nnBelgium. Exposure Limit Values.nComponents                 Type  Value      FormnAluminum Oxide; Alumina    TWA   1 mg/m3    Respirable fraction.n(CAS 1344-28-1)nGlycerol (CAS 56-81-5)     TWA   10 mg/m3   Mist.nKEROSENE (CAS 8008-20-6)   TWA   200 mg/m3  Vapor.nnBulgaria. OELs. Regulation No 13nAluminum Silicate (CAS 66402-68-4) TWA 6 mg/m3 Inhalable fraction; 3 mg/m3 Respirable fraction.nKEROSENE (CAS 8008-20-6)          TWA 300 mg/m3nnCroatia. ELVsnAluminum Oxide; Alumina (CAS 1344-28-1) MAC 4 mg/m3 Respirable dust; 10 mg/m3 Total dust.nGlycerol (CAS 56-81-5)              MAC 10 mg/m3nnCzech Republic. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 0.1 mg/m3 Respirable dust.nGlycerol (CAS 56-81-5) Ceiling 15 mg/m3 Mist; TWA 10 mg/m3 Mist.nnDenmark. Exposure Limit ValuesnAluminum Oxide; Alumina (CAS 1344-28-1) TLV 5 mg/m3 Total; 2 mg/m3 Respirable.nnEstonia. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 4 mg/m3 Respirable dust; 10 mg/m3 Total dust.nGlycerol (CAS 56-81-5)              TWA 10 mg/m3nnFinland. Workplace Exposure LimitsnGlycerol (CAS 56-81-5)              TWA 20 mg/m3nnFrance. VLEPnAluminum Oxide; Alumina (CAS 1344-28-1) VME 10 mg/m3nGlycerol (CAS 56-81-5)              VME 10 mg/m3 Aerosol.nnGermany. DFG MAK ListnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 4 mg/m3 Inhalable dust; 1.5 mg/m3 Respirable dust.nGlycerol (CAS 56-81-5)              TWA 50 mg/m3 Inhalable fraction.nnGermany. TRGS 900nAluminum Oxide; Alumina (CAS 1344-28-1) AGW 10 mg/m3 Inhalable fraction; 1.25 mg/m3 Respirable fraction.nnGreece. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 5 mg/m3 Inhalable; 10 mg/m3 Respirable.nGlycerol (CAS 56-81-5)              TWA 10 mg/m3nnHungary. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 6 mg/m3 Respirable.nnIceland. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 10 mg/m3nnIreland. Occupational Exposure LimitsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 4 mg/m3 Respirable dust; 10 mg/m3 Total inhalable dust.nGlycerol (CAS 56-81-5)              TWA 10 mg/m3 Mist.nnItaly. Occupational Exposure LimitsnKEROSENE (CAS 8008-20-6)           TWA 200 mg/m3 Non-aerosol.nnLatvia. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 6 mg/m3 Decomposition aerosol; 4 mg/m3.nnNorway. Administrative NormsnAluminum Oxide; Alumina (CAS 1344-28-1) TLV 10 mg/m3nnPoland. MACsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 2.5 mg/m3 Inhalable; 1.2 mg/m3 Respirable.nGlycerol (CAS 56-81-5)              TWA 10 mg/m3 Inhalable fraction.nKEROSENE (CAS 8008-20-6)           STEL 300 mg/m3; TWA 100 mg/m3nnPortugal. VLEsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 10 mg/m3nGlycerol (CAS 56-81-5)              TWA 10 mg/m3nKEROSENE (CAS 8008-20-6)           TWA 200 mg/m3 Non-aerosol.nnRomania. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) STEL 5 mg/m3 Aerosol; 1.2 ppm Aerosol.n                                     TWA 2 mg/m3 Aerosol; 0.5 ppm Aerosol.nnSlovakia. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 4 mg/m3 Inhalable fraction; 1.5 mg/m3 Respirable fraction; 0.1 mg/m3nGlycerol (CAS 56-81-5)              TWA 10 mg/m3nnSpain. Occupational Exposure LimitsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 10 mg/m3nGlycerol (CAS 56-81-5)              TWA 10 mg/m3 Mist.nnSweden. OELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 5 mg/m3 Total dust; 2 mg/m3 Respirable dust.nnSwitzerland. SUVAnAluminum Oxide; Alumina (CAS 1344-28-1) STEL 24 mg/m3 Fume and respirable dust; TWA 3 mg/m3 Respirable dust; 3 mg/m3 Fume and respirable dust.nGlycerol (CAS 56-81-5)              STEL 100 mg/m3 Inhalable dust; TWA 50 mg/m3 Inhalable dust.nnUK. EH40 WELsnAluminum Oxide; Alumina (CAS 1344-28-1) TWA 4 mg/m3 Respirable dust; 10 mg/m3 Inhalable dust.nGlycerol (CAS 56-81-5)              TWA 10 mg/m3 Mist.

Biological limit values: No biological exposure limits noted for the ingredient(s).

Recommended monitoring procedures: Follow standard monitoring procedures.

Derived no-effect level (DNEL): Not available.

Predicted no-effect concentrations (PNECs): Not available.

8.2 Exposure controls:

Engineering controls: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Where applicable, use process enclosures, local exhaust ventilation or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels at an acceptable level.

Personal protective equipment:

• General: PPE should be selected according to CEN standards and in consultation with the supplier.
• Eye/face protection: Chemical respirator with organic vapour cartridge and full facepiece (provides both respiratory and eye protection).
• Hand protection: Wear appropriate chemical-resistant gloves. Suitable types should be confirmed with the glove supplier.
• Other skin protection: Use an impervious apron as needed.
• Respiratory protection: Chemical respirator with organic vapour cartridge and full facepiece when ventilation is inadequate.
• Thermal hazards: Wear appropriate thermal protective clothing if there is a risk of thermal exposure.

Hygiene measures: Observe good personal hygiene: wash after handling and before eating, drinking or smoking. Wash work clothing and PPE regularly to remove contaminants.

Environmental exposure control: Environmental manager must be informed of all major releases.

Appearance: Viscous, yellow cream

Physical state: Liquid

Form: Liquid, cream

Odour: Vanilla

Odour threshold: Not available

pH: 8.2 – 9.2

Melting point / Freezing point: Not available

Initial boiling point and range: 3734.24 °F (2056.8 °C) (estimated)

Flash point: 145.0 °F (62.8 °C)

Evaporation rate: Not available

Flammability (solid, gas): Not applicable

Lower flammability limit: 0.7% (estimated)

Upper flammability limit: 5% (estimated)

Vapour pressure: 0.06 hPa (estimated)

Vapour density: Not available

Relative density: Not available

Solubility in water: Not available

Solubility in other solvents: Not available

Partition coefficient (n-octanol/water): Not available

Auto-ignition temperature: 594.01 °F (312.23 °C) (estimated)

Decomposition temperature: Not available

Viscosity: 150,000 – 295,000 cP at 68 °F (20 °C)

Density: 10.64 lbs/gal

Kinematic viscosity: 156,703 cSt at 68 °F (20 °C)

VOC (weight %): 16.95%

Explosive properties: Not explosive.

Oxidising properties: Not oxidising.

Reactivity: The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use.

Conditions to avoid: Avoid temperatures exceeding the flash point. Avoid contact with incompatible materials.

Incompatible materials: Strong oxidizing agents, chlorine.

Hazardous decomposition products: No hazardous decomposition products are known under normal conditions of use.

General: Occupational exposure to the substance or mixture may cause adverse effects.

Likely routes of exposure:

• Inhalation: May cause damage to organs through prolonged or repeated exposure by inhalation.
• Skin contact: No adverse effects due to skin contact are expected under normal conditions of use.
• Eye contact: Direct contact with eyes may cause temporary irritation.
• Ingestion: May cause discomfort if swallowed; ingestion is not expected to be a primary route of occupational exposure.

Symptoms: Exposure may cause temporary irritation, redness or discomfort.

Acute toxicity: No specific acute toxicity data available for the mixture.

Skin corrosion/irritation: Data insufficient for classification; not expected to be corrosive based on available information.

Serious eye damage/irritation: Direct contact may cause temporary irritation.

Respiratory sensitisation: Data insufficient for classification.

Skin sensitisation: Data insufficient for classification.

Germ cell mutagenicity: Data insufficient for classification.

Carcinogenicity: Data insufficient for classification.

Reproductive toxicity: Data insufficient for classification.

STOT – Single exposure: Data insufficient for classification.

STOT – Repeated exposure: Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard: Data insufficient for classification.

Mixture vs. substance information: No additional mixture-specific data available beyond component information.

Toxicity: The product is not classified as environmentally hazardous. However, large or frequent spills may have harmful or damaging effects on the environment.

Persistence and degradability: No data available on the degradability of this product.

Bioaccumulative potential: No data available.

Bioconcentration factor (BCF): Not available.

Mobility in soil: No data available.

Results of PBT and vPvB assessment: Not available.

Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Residual waste: Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see disposal instructions).

Contaminated packaging: Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

EU waste code: To be assigned in discussion between the user, the producer and the waste disposal company.

Disposal methods: Collect and reclaim or dispose of in sealed containers at licensed waste disposal sites. Dispose of contents/container in accordance with local/regional/national/international regulations.

Special precautions: Dispose in accordance with all applicable regulations and ensure all handling of waste follows safe practices.

ADR (Road): Not regulated as dangerous goods.

RID (Rail): Not regulated as dangerous goods.

ADN (Inland waterways): Not regulated as dangerous goods.

IATA (Air): Not regulated as dangerous goods.

IMDG (Sea): Not regulated as dangerous goods.

Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not established.

EU regulations:

• Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I and II: Not listed.
• Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex I: Not listed.
• Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I (parts 1, 2, 3) and Annex V: Not listed.
• Regulation (EC) No. 166/2006 Annex II (Pollutant Release and Transfer Register): Not listed.
• Regulation (EC) No. 1907/2006, REACH Article 59(10) Candidate List: Not listed.
• REACH Annex XIV (Substances subject to authorisation): Not listed.
• REACH Annex XVII (Restrictions on marketing and use): Not listed.

Worker protection directives:

• Directive 2004/37/EC (carcinogens and mutagens at work): Not listed.
• Directive 92/85/EEC (pregnant/breastfeeding workers): Not listed.
• Directive 98/24/EC (chemical agents at work): applicable to Solvent Naphtha (Petroleum), Medium Aliph. (CAS 64742-88-7).
• Directive 94/33/EC (young people at work): applicable to Solvent Naphtha (Petroleum), Medium Aliph. (CAS 64742-88-7).

New Zealand:

New Zealand ERMA Register of Hazardous Substances: HSNO Approval HSR002525 – Cleaning Products (Combustible) Group Standard 2006.

National regulations: The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006, as amended. Follow national regulations for work with chemical agents.

Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for this mixture.

Abbreviations: Not specifically listed beyond standard regulatory abbreviations.

References: Not available (as stated in the SDS).

Evaluation method: Classification for health and environmental hazards is derived from a combination of calculation methods and test data, where available.

Full text of H-statements referenced:

• H304: May be fatal if swallowed and enters airways.
• H372: Causes damage to organs through prolonged or repeated exposure.

Revision information: This document has undergone significant changes and should be reviewed in its entirety.

Training: Follow training instructions when handling this material.

Disclaimer: Presta Products cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the useru2019s responsibility to ensure safe conditions for handling, storage and disposal of the product and to assume liability for loss, injury, damage or expense due to improper use. The information in this Safety Data Sheet is correct to the best of the companyu2019s knowledge, information and belief at the date of publication and is intended as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not a warranty or quality specification and relates only to the specific material designated; it may not be valid when used in combination with any other materials or in any process unless specified.